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Oh thats horrid! I hope for your sake it isn't a cigarette burn a friend had a party and some idiot put a cigarette on the edge of the marble vanity and let it burn down, they had to replace the marble... however, you can remove some stains, but do you know what it is, there is this fantastic article on this site... http://eurotechmarble.com/removingstains.htm which I have pasted the relevant part of below, but if your particular stain isn't in there, try here (they explain how to apply poultice and NOT to wipe but blot at stain etc) http://www.housekeepingchannel.com/a_121-Removing_Stains_From_Stone_Tile_and_Concrete and these people sell marble benchtops and have some good ideas too, http://www.kitchenbenchtops.com/0/3/3/Marble-Benchtops.html If I were you I would review them all before deciding what may work, because you can do more harm than good if you put the wrong thing onto marble. Good Luck and I hope it comes out! Marble and natural stone are porous materials. This porosity is why it stains so easily. It is also why stains can be removed. All that's needed to remove a stain is to reverse the staining process. In other words. the stone has literally absorbed the stain and we simply re-absorb it into a different material This different material is what we call a poultice. A poultice can be made with powdered whiting and hydrogen peroxide or a chemical reducing agent-depending on the nature of the stain. Whiting is sold in most paint stores. The poultice should be made and applied as described for removal of each particular stain. Some of the more common poulticing materials and powders are: cotton balls paper towels ( maybe Rosie is right) gauze pads Stain Removal Guide All solutions are given starting with the gentlest method first. All the chemical solutions mentioned can be purchased at most hardware stores or from a marble supply distributor. 1. Iron Stains (rust) Poultice with on the the following: a. Sodium citrate and glycerin or b. Ammononium Oxalate or c. Oxalic Acid or d. Orthophosphoric Acid and Sodium Salt of EDTA in water or e. Dilute Hydrofluoric Acid or f. cannot be removed, is part of the stone 2. Ink Poultice with one of the following: a. Light colored marbles only use Bleach or Hydrogen Peroxide; b. Dark marbles use Lacquer Thinner or Acetone; c. Methyl Chloride 3. Oil Based Stains (grease, cooking oil, tar, food stains, etc.) Clean with: a. Scouring Power with Bleach or b. Household Detergent or c. Ammonia or d. Mineral spirits or poultice with: e. Baking Soda or f. Mineral Spirits or g. Methyl chloride 4. Organic Stains (paper, tea, coffee, cosmetics, fruit, tobacco, etc.) a. Pour Hydrogen Peroxide 35% directly on stain and add a few drops of ammonia, leave until bubbling stop ors b. Repeat above but add poultice or c. Acetone or Toluene or Xylene 5. Efflorescence Poultice with: a. Distilled Water 6. Copper Stains Poultice with: a. Ammonium Chloride or b. Ammonium Hydroxide 7. Biological Stains (Lichens, algae, moss, fungi, mildew, etc.) Clean with: a. Dilute Ammonia or b. Bleach or c. Hydrogen Peroxide or d. Sodium Hypochiorite 8. Wax (Acrylic yellowing coatings) Strip with: Alkaline Stripper 9. Urethane Coatings a. Methyl Chloride or b. Grinding 10. Crystallization coatings a. Strip with Oxalic Acid based Stripper or b. Methyl Chloride 11. Paint a. Alkaline Paint Remover b. Methyl Chloride 12. Grout and Thin Set Residue a. Scrub with neutral cleaner and red pad or b. Re-polish 13. Scratches a. Re-polish or b. Re-hone 14. Streaking a. Buff with felt pad-dry or b. 0000 Steel wool-dry or c. Re-polish 15. Acid/Alkaline Etching a. Re-polish or b. Re-hone 16. Stuns/Crystal Fractures Re-hone 17.Water Spots and Rings a. Buff with a dry 0000 Steel wool or b. Re-polish or c. Re-hone 18. Discoloration Clean with: a. Alkaline Stripper or Poultice with: b. Bleach or c. Hydrogen Peroxide or d. Re-hone and polish 19. Swirl Marks from steel wool a. Re-polish or b. Re-hone 20. Random Dull Spots a. Check for etching or b. Re-polish Frediric M. Hueston has a degree in Chemistry and is also an experienced and accomplished marble and stone craftsman, Founder and president of Cambridge Floor Care Systems, based in Winter Park, Florida. Hueston is a recognized leader in the marble and stone care and restoration field.